const BaseTable:string='ABCDEFGHIJKLMNOPQRSTUVWXYZabcdefghijklmnopqrstuvwxyz0123456789+/=';
var
AuthSucc:boolean;// 是否需要密码验证
FromAddress,BodyText:string;
function DecodeBase64(Source:string):string; //解码函数
function FindInTable(CSource:char):integer; //
function EncodeBase64(Source:string):string; //编码函数
implementation
function FindInTable(CSource:char):integer;
begin
result:=Pos(string(CSource),BaseTable)-1;
end;
////
function DecodeBase64(Source:string):string;
var
SrcLen,Times
,i:integer;
x1,x2,x3,x4,xt:byte;
begin
result:='';
SrcLen:=Length(Source);
Times:=SrcLen div 4;
for i:=0 to Times-1 do
begin
x1:=FindInTable(Source[1+i*4]);
x2:=FindInTable(Source[2+i*4]);
x3:=FindInTable(Source[3+i*4]);
x4:=FindInTable(Source[4+i*4]);
x1:=x1 shl 2;
xt:=x2 shr 4;
x1:=x1 or xt;
x2:=x2 shl 4;
result:=result+chr(x1);
if x3= 64 then break;
xt:=x3 shr 2;
x2:=x2 or xt;
x3:=x3 shl 6;
result:=result+chr(x2);
if x4=64 then break;
x3:=x3 or x4;
result:=result+chr(x3);
end;
end;
/////
function EncodeBase64(Source:string):string;
var
Times,LenSrc,i:integer;
x1,x2,x3,x4:char;
xt:byte;
begin
result:='';
LenSrc:=length(Source);
if LenSrc mod 3 =0 then Times:=LenSrc div 3
else Times:=LenSrc div 3 + 1;
for i:=0 to times-1 do
begin
if LenSrc >= (3+i*3) then
begin
x1:=BaseTable[(ord(Source[1+i*3]) shr 2)+1];
xt:=(ord(Source[1+i*3]) shl 4) and 48;
xt:=xt or (ord(Source[2+i*3]) shr 4);
x2:=BaseTable[xt+1];
xt:=(Ord(Source[2+i*3]) shl 2) and 60;
xt:=xt or (ord(Source[3+i*3]) shr 6);
x3:=BaseTable[xt+1];
xt:=(ord(Source[3+i*3]) and 63);
x4:=BaseTable[xt+1];
end
else if LenSrc>=(2+i*3) then
begin
x1:=BaseTable[(ord(Source[1+i*3]) shr 2)+1];
xt:=(ord(Source[1+i*3]) shl 4) and 48;
xt:=xt or (ord(Source[2+i*3]) shr 4);
x2:=BaseTable[xt+1];
xt:=(ord(Source[2+i*3]) shl 2) and 60;
x3:=BaseTable[xt+1];
x4:='=';
end else
begin
x1:=BaseTable[(ord(Source[1+i*3]) shr 2)+1];
xt:=(ord(Source[1+i*3]) shl 4) and 48;
x2:=BaseTable[xt+1];
x3:='=';
x4:='=';
end;
result:=result+x1+x2+x3+x4;
end;
end;
'==================================================================
procedure TWebModule1.NMSMTP1Connect(Sender: TObject);
begin
if nmsmtp1.ReplyNumber = 250 then
nmsmtp1.Transaction('auth login'); //开始认证
if nmsmtp1.ReplyNumber =334 then //返回值为334，让你输入用BASE64编码后的用户名
nmsmtp1.Transaction(EncodeBase64('shadow'));// 用户名aaaaa
if nmsmtp1.ReplyNumber =334 then // 返回值为334，让你输入用BASE64编码后的用户密码
nmsmtp1.Transaction(EncodeBase64('xujian79')); //密码为123456
if nmsmtp1.ReplyNumber =235 then
begin
AuthSucc:=true;
end;
end;
'===================================================
不过建议还是使用Indy吧，使用很方便
